Chimie generale by Zumdahl S.S.

By Zumdahl S.S.

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Lanthanide Metal-Catalyzed Addition. . . . . . . . . .. 31 33 3 Transition Metal-Catalyzed Addition of Hydrogen Phosphonate . 2 Addition to Alkynes . . . . . . . . . . . . . . . Addition to Alkenes and Dienes . . . . . . . . . . . 36 41 4 Transition Metal-Catalyzed Addition of Secondary Phosphine Oxides . . . . . . . . . . . 2 Addition to Alkynes . . . . . . . . . . . . . . . Phosphinic Acid-Induced Reversal of Regioselectivity .

50 Addition of Hypophosphite to Unsaturated Compounds . . . 3 6 .. 26 27  Springer-Verlag Berlin Heidelberg 2004 26 Masato Tanaka Conclusion . . . . . . . . . . . . . . . . . . 53 References . . . . . . . . . . . . . . . . . . . . 53 7 1 Introduction Organophosphorus compounds, useful in diverse applications, are still produced by classic methods such as Grignard and Arbuzov reactions. The drawback of these methods lies in that they are substitution reactions, which result in the formation of undesired co-products.

26 2 Metal Complex-Catalyzed Addition of the P(III)-H Bond to Unsaturated Compounds . . . . . . . . . . . . . 4 Transition Metal-Catalyzed Addition of PH3 to Formaldehyde . Transition Metal-Catalyzed Addition of PH3 to Alkenes . . . Transition Metal-Catalyzed Addition of the P(III)-H Bond to Alkynes . . . . . . . . . . . . . . . . . Lanthanide Metal-Catalyzed Addition. . . . . . . . . .. 31 33 3 Transition Metal-Catalyzed Addition of Hydrogen Phosphonate .

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