Catalysis in application: [proceedings of the International by S.D. Jackson, J.S.J. Hargreaves, D. Lennon

By S.D. Jackson, J.S.J. Hargreaves, D. Lennon

Catalysis in software provides a photograph of the main up to date advancements within the box of utilized catalysis. assurance is especially within the parts of hydrogenation, dehydrogenation, chiral catalysis, environmental catalysis and catalyst deactivation, combining a distinct mixture of chemistry and chemical engineering.With its wide-ranging assurance, this publication could be a great addition to the cabinets of each practitioner in catalysis, either in and academia.

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Example text

However, the decrease in hydrogen partial pressure is not sufficient to explain the magnitude of the change in the paraffin to olefin ratio for the initial runs, although it might explain the decrease observed in the later runs (for example run 19). 2 However, metal sites not only increase the rate of dehydrogenation, but also the rate of hydrogenation. Since the feed is already olefinic, it is expected that the metal sites should promote both hydrogenation and aromatisation. The decrease in paraffin to olefin ratio therefore suggests a preferential deactivation of the metal sites.

Dev, 1976,15, 291. R. Acharya and R. , 1990,68(2), 89. H. A. Fuentes, Catalyst Deactivation 1997, Studies in Surface Science and Catalysis, Vol 111, Elsevier, Amsterdam 1997. P. Breen', R. Burch', J. Gomez-Lopez', K. Griffin', M. Hayes' ' ' School of Chemistry, Queen's University Belfast, David Keir Building, Stranmillis Road, Belfast BT9 5AG, N. Ireland Johnson Matthey plc, Orchard Road, Royston, Hertfordshire, SG8 5HE, UK 1 INTRODUCTION The selective hydrogenation of a,,f3-unsaturated carbonyls is a key step in the manufacture of pharmaceuticals and flavours and fragrances.

Ind. Eng. Chem. , 1996,35, 3055. De Lucas, A. Canizares, P. Duran, A. , Appl. Catal. A, 1997,154,221. K. Viswanadham, N. Ray, N. K. , Appl. Catal. A , 2001, 205, 1. Viswanadham, N. G. , J. Mol. Catal. , 1997, 125, L87. V. B. A. J. , Stud. Surf: Sci. , 2001, 139, 77. R. F. J. H. C. , Appl. Catal. A , 1997,159, 187. A. , Catal. Rev. , 1996,38, 101. Mole, T. R. , Appl. , 1985, 17, 141. Bhattacharya, D. , Appl. Catal. A , 1996, 141, 105. Nakamura, I. , Catal. Today, 1996,31,335. A. , Catal. Today, 1996,31,207.

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